(2-Methylphenyl)(phenyl)methanol
نویسندگان
چکیده
In the title compound, C(14)H(14)O, the two benzene rings are almost orthogonal [dihedral angle = 87.78 (8) °]. The hy-droxy group lies approximately in the plane of its attached benzene ring [O-C-C-C torsion angle = -17.47 (17)°], and the hydroxyl and methyl groups lie to the same side of the mol-ecule and are gauche to each other. In the crystal, a hexa-meric aggregate mediated by a ring of six O-H⋯O hydrogen bonds occurs, generating an R(6) (6)(12) loop.
منابع مشابه
(E)-1-{2-Hydroxy-5-[(4-methylphenyl)diazenyl]phenyl}ethanone
The structure of the title compound, C(15)H(14)N(2)O(2), an azo dye, displays a trans configuration with respect to the N=N bridge. The dihedral angle between the aromatic rings is 5.06 (8)°. The mol-ecular conformation is stabilized by a strong intra-molecular O-H⋯O hydrogen bond. In the crystal, inter-molecular C-H⋯O hydrogen bonds occur.
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In the title compound, C(15)H(16)N(2)O(3)S, the central C-S(=O)(2)N(H)-C unit is twisted, with a C-S-N-C torsion angle of -56.4 (2)°. The benzene rings form a dihedral angle of 49.65 (15)° with each other. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, generating a three-dimensional network.
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The title compound, [Bi(C(7)H(7))(2)(C(9)H(12)N)], was obtained by treating chlorodi(p-tol-yl)bis-muthane with o-lithio-N,N-dimethyl-benzyl-amine. An intra-molecular Bi⋯N nonbonding inter-action is observed in the distorted trigonal triaryl-bis-muth coordination of the title compound.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010